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This paper presents a high-resolution lake-level record for the Holocene at Lago Preola (Sicily, southern Italy) based on a specific sedimentological approach, with a chronology derived from AMS radiocarbon dates. It gives evidence of three major successive palaeohydrological periods, with (1) a pronounced dryness during the early Holocene until ca 10300 cal BP, (2) a highstand from ca 10300 to 4500 cal BP, and (3) a marked lowstand from 4500 cal BP to present. Large amplitude lake-level fluctuations characterise two transition phases at ca 10300–9000 and 6400–4500 cal BP. Period 2 was interrupted between 8300 and 7000 cal BP by a dry phase that was punctuated to ca 7300 cal BP by the deposition of a tephra from neighbouring Pantelleria Island. Comparisons of the Preola record with other palaeohydrological records along north–south and west–east transects in the Mediterranean show contrasting patterns of hydrological changes: north (south) of around 40°N latitude, the records highlight a mid-Holocene period characterised by lake-level minima (maxima). Humid mid-Holocene conditions over the Mediterranean south of 40°N were probably linked to a strong weakening of the Hadley cell circulation and of monsoon winds. We suggest that the maximum of humidity in the Mediterranean during the mid-Holocene was characterised by humid winters to the north of 40°N and humid summers to the south. On a multi-centennial scale, the high-resolution palaeohydrological reconstructions in the central Mediterranean area reveal a strong climate reversal around 4500–4000 cal BP, with contrasting changes in the hydrological cycle. In addition to seasonal and inter-hemispherical changes related to orbital forcing, this major oscillation might be related to non-linear responses of the climatic system to the gradual decrease in summer insolation at northern latitudes. Another major climate oscillation around 7500–7000 cal BP may have resulted from the combined effects of (1) a strong rate of change in insolation, and (2) variations in solar activity. Finally, comparisons of the Preola lake-level record with Sicilian pollen records suggest a strong influence of moisture availability on vegetation development in Sicily. Very dry early Holocene conditions probably prevented the expansion of coastal evergreen forests, while decreasing moisture availability since the onset of the late Holocene may have exacerbated effects of intensive land-use.  相似文献   
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In numerical weather prediction and climate models, planetary boundary-layer (PBL) clouds are linked to subgrid-scale processes such as shallow convection. A comprehensive statistical analysis of large-eddy simulations (LES), obtained for warm PBL cloud cases, is carried out in order to characterize the distributions of the horizontal subgrid cloud variability. The production of subgrid clouds is mainly associated with the variability of the total water content. Nevertheless, in the case of PBL clouds, the temperature variability cannot be completely discarded and the saturation deficit, which summarizes both temperature and total water fluctuations, provides a better representation of the cloud variability than the total water content. The probability density functions (PDFs) of LES saturation deficit generally have the shape of a main asymmetric bell-shaped curve with a more or less distinct secondary maximum specific to each type of PBL clouds. Unimodal theoretical PDFs, even those with a flexible skewness, are not sufficient to correctly fit the LES distributions, especially the long tail that appears for cumulus clouds. They do not provide a unified approach for all cloud types. The cloud fraction and the mean cloud water content, diagnosed from these unimodal PDFs, are largely underestimated. The use of a double Gaussian distribution allows correction of these errors on cloud fields and provides a better estimation of the cloud-base and cloud-top heights. Eventually, insights for the design of a subgrid statistical cloud scheme are provided, in particular a new formulation for the weight of the two Gaussian distributions and for the standard deviation of the convective distribution.  相似文献   
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This paper presents quantitative climate estimates for the last millennium, using a multi-proxy approach with pollen and lake-level data from Lake Joux (Swiss Jura Mountains). The climate reconstruction, based on the Modern Analogue Technique, indicates warmer and drier conditions during the Medieval Warm Period (MWP). MWP was preceded by a short-lived cold humid event around AD 1060, and followed by a rapid return around AD 1400 to cooler and wetter conditions which generally characterize the Little Ice Age (LIA). Around AD 1450 (solar Spörer minimum), the LIA attained a temperature minimum and a summer precipitation maximum. The solar Maunder minimum around AD 1690 corresponded at Joux to rather mild temperatures but maximal annual precipitation. These results generally agree with other records from neighbouring Alpine regions. However, there are differences in the timing of the LIA temperature minimum depending on the proxy and/or the method used for the reconstruction. As a working hypothesis, the hydrological signal associated with the MWP and LIA oscillations at Lake Joux may have been mainly driven by a shift around AD 1400 from positive to negative NAO modes in response to variations in solar irradiance possibly coupled with changes in the Atlantic meridional overturning circulation.  相似文献   
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The variability of Quaternary landforms preserved in the Tabernas basin of southeast (SE) Spain raises numerous questions concerning the roles of external forcing mechanisms (e.g. tectonics and/or climate) and internal landscape properties (e.g. lithological controls) in the evolution of the basin‐wide fluvial system over Late Quaternary timescales. In this study, we apply the FLUVER2 numerical model to investigate the significance of these landscape controls upon patterns of landscape evolution. We highlight the complications of generating realistic input datasets for use in the modelling of long‐term landscape evolution (e.g. discharge and runoff datasets). Model outputs are compared to extensive field mapping of fluvial terraces, their sedimentary architecture and optically stimulated luminescence dating results of the terraces. The results demonstrate the significance of non‐linear rates of flexural tectonic uplift towards the west of the Tabernas Basin which have controlled base levels throughout the Quaternary and promoted the formation of a series of diverging fluvial terraces. Our numerical model results further highlight the importance of climate cycles upon river terrace formation. Basin‐wide aggradation events were modelled during the transition from Marine Isotope Stage (MIS) 6 to 5 and the Last Glacial Maximum (LGM) as supported by field evidence. This aggradational pattern supports the regional hypothesis of terrace formation during global glacial cycles and cold‐to‐warm stage transitions and supports the use of sea surface temperature climate proxy data in the modelling exercise. The availability of sediments derived from the surrounding hillslopes and adjacent alluvial fans explains the generation of substantial terrace aggradations. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   
27.
The distribution of arsenic (As(III), As(V)) and iron (Fe(II), Fe(III)) species was monitored during 1 year in a borehole drilled in the Carnoulès tailings impoundment which contains As-rich pyrite. The concentrations of total As and Fe in subsurface waters exhibited strong variations over one year, which were controlled by dissolved oxygen concentrations. At high oxygen levels, extremely high As (up to 162 mM) and Fe (up to 364 mM) concentrations were reached in the borehole, with the oxidised species predominant. As and Fe concentrations decreased 10-fold under oxygen-deficient conditions, as a result of pH increase and subsequent precipitation of As(V) and Fe(III). From drill core sections, it appeared that at low dissolved oxygen levels, As(III) was primarily released into water by the oxidation of As-rich pyrite in the unsaturated zone. Subsequent As and Fe precipitation was promoted during transport to the saturated zone; this reaction resulted in As enrichments in the sediment below the water table compared to the original content in pyrite, together with the formation of As-rich (up to 35 wt% As) ferruginous material in the unsaturated zone. High amounts of As(V) were released from these secondary phases during leaching experiments with oxygenated acid sulfate-rich waters; this process is believed to contribute to As(V) enrichment in the subsurface waters of the Carnoulès tailings during periods of high dissolved oxygen level.  相似文献   
28.
High-temporal resolution analyses of pollen, chironomid, and lake-level records from Lake Lautrey provide multi-proxy, quantitative estimates of climatic change during the Late-Glacial period in eastern France. Past temperature and moisture parameters were estimated using modern analogues and ‘plant functional types’ transfer-function methods for three pollen records obtained from different localities within the paleolake basin. The comparison of these methods shows that they provide generally similar climate signals, with the exception of the Bölling. Comparison of pollen- and chironomid-based temperature of the warmest month reconstructions generally agree, except during the Bölling. Major abrupt changes associated with the Oldest Dryas/Bölling, Alleröd/Younger Dryas, and the Younger Dryas/Preboreal transitions were quantified as well as other minor fluctuations related to the cold events (e.g., Preboreal oscillation). The temperature of the warmest month increased by ∼5°C at the start of Bölling, and by 1.5°-3°C at the onset of the Holocene, while it fell by ca. 3° to 4°C at the beginning of Younger Dryas. The comparative analysis of the results based on the three Lautrey cores have highlighted significant differences in the climate reconstructions related to the location of each core, underlining the caution that is needed when studying single cores not taken from deepest part of lake basins.  相似文献   
29.
Eleven monthly estuarine profiles of dissolved inorganic germanium (Gei) and silica (Si) in a natural, pristine river/bay system demonstrate that Ge-removal and -input parallel the seasonal silica cycle, reflecting Ge-uptake by and -dissolution from diatoms. The Ge/Si atom ratio of the river is 0.6 ± 0.15 × 10?6, which is near the average value for continental granites and for uncontaminated, remote, natural rivers (0.7 ± 0.3 × 10?6). The GeSi ratio escaping this estuary to the ocean is 0.8 × 10?6, reflecting some estuarine enhancement of the fluvial Ge-flux, probably due to release of Gei from fluvial particulates. Nevertheless, the post-estuarine GeSi ratio is not significantly different from the continental crustal ratio but is very different from the ratio in sea-floor hot springs and mid-ocean ridge hydrothermal plumes (4 ± 2 × 10?6) and in oceanic basalts (2.6 × 10?6). Thus natural estuarine processes do not obscure the contrasting GeSi signatures entering the ocean from dissolution of continental and sea-floor silicates.  相似文献   
30.
The smectite-to-chlorite conversion is investigated through long-duration experiments (up to 9 years) conducted at 300 °C. The starting products were the Wyoming bentonite MX80 (79 % smectite), metallic iron and magnetite in contact with a Na–Ca chloride solution. The predominant minerals in the run products were an iron-rich chlorite (chamosite like) and interstratified clays interpreted to be chlorite/smectite and/or corrensite/smectite, accompanied by euhedral crystals of quartz, albite and zeolite. The formation of pure corrensite was not observed in the long-duration experiments. The conversion of smectite into chlorite over time appears to take place in several steps and through several successive mechanisms: a solid-state transformation, significant dissolution of the smectite and direct precipitation from the solution, which is over-saturated with respect to chlorite, allowing the formation of a chamosite-like mineral. The reaction mechanisms are confirmed by X-ray patterns and data obtained on the experimental solutions (pH, contents of Si, Mg, Na and Ca). Because of the availability of some nutrients in the solution, total dissolution of the starting smectite does not lead to 100 % crystallization of chlorite but to a mixture of two dominant clays: chamosite and interstratified chlorite/smectite and/or corrensite/smectite poor in smectite. The role of Fe/(Fe + Mg) in the experimental medium is highlighted by chemical data obtained on newly formed clay particles alongside previously published data. The newly formed iron-rich chlorite has the same composition as that predicted by the geothermometer for diagenetic to low-grade metamorphic conditions, and the quartz + Fe-chlorite + albite experimental assemblage in the 9-year experiment is close to that fixed by water–rock equilibrium.  相似文献   
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